Chemical and Pharmaceutical Bulletin · 1972 · 28 citations · 0 references
Natural SciencesBiochemistryChemistryOrganic ChemistrySteroid StructureTerpenoid BiosynthesisAbsolute Configuration AssignmentAbsolute Configuration DeterminationSpectroscopic CharacterizationTerpene Compounds
On the basis of chemical and spectroscopic evidence, the structure and absolute configuration of lasiokaurin and lasiodonin, which were isolated from Isodon lasiocarpus (HAYATA) KUDO, were established as ent-7β, 20-epoxy-1β-acetoxy-15-oxo-16-kaurene-6α, 7α, 14α-triol (II) and ent-7β, 20-epoxy-15-oxo-16-kaurene-1β, 6α, 7α, 11α-tetraol (VIII), respectively.