Publication | Closed Access
The Synthesis and Crystal Structures of Two-Dimensional Coordination Polymers of Ph<sub>2</sub>P(O)−CH<sub>2</sub>CH<sub>2</sub>−P(O)Ph<sub>2</sub> and Ph<sub>2</sub>P(O)−C<sub>5</sub>H<sub>3</sub>N−P(O)Ph<sub>2</sub> with Praseodymium
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Citations
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References
2004
Year
Reactions of Pr(NO3)3 with Ph2P(O)-CH2CH2-P(O)Ph2 and Ph2P(O)-C5H3N-P(O)Ph2 yielded layered network coordination polymers with bidentate ligands spanning the lanthanide atoms in a bridging fashion. The praseodymium cations with "spacer" ligands form two-dimensional building blocks assembling into either square grid or herringbone network.
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