Publication | Closed Access
Redox-Neutral Atom-Economic Rhodium-Catalyzed Coupling of Terminal Alkynes with Carboxylic Acids Toward Branched Allylic Esters
169
Citations
48
References
2011
Year
Terminal AlkynesChemical EngineeringCross-coupling ReactionEngineeringAllylic EstersAlkene MetathesisOrganic ChemistryOrganometallic CatalysisCatalysisChemistryWide RangeAsymmetric CatalysisEnantioselective SynthesisBiomolecular Engineering
A new method for the preparation of a wide range of branched allylic esters from terminal alkynes that proceeds via a redox-neutral propargylic CH activation employing a rhodium(I)/DPEphos catalyst is reported.
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