Organic Letters · 2011 · 73 citations · 7 references
Natural SciencesChemistryMaterials ScienceMaterials ChemistryOptical MaterialsOrganic ChemistryPhotochemical SynthesisPhotochemistryPhotochromic MaterialsFatigue ResistancePhotochemical FunctionalizationReversibilitySynthetic Receptor EngineeringUv Light ApplicationsVisible Light Effects
A versatile amide- and urea-functionalized dithienylethene has been successfully synthesized. Upon irradiation with UV or visible light, the compound showed excellent fatigue resistance. As a synthetic receptor, the dithienylethene displayed switchable affinities for Cl(-) and Br(-) anions when the UV/vis light was introduced. The switchable binding ability also had good reversibility.
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