33rd Plasmadynamics and Lasers Conference · 2002 · 25 citations · 37 references
EngineeringAerospace EngineeringMeteorologyAtmospheric ThermodynamicsHeat TransferTransport PhenomenaAtmospheric CompositionBoltzmann Transport EquationPlanetary AtmospheresTransport PropertiesAtmospheric Gas Mixture ModelingGas Transport PropertiesHarmonic Oscillator ApproximationLocal Thermodynamic Equilibrium ApproximationLocal Thermodynamic Equilibrium ModelingPotential Energy CurvesThermodynamic AnalysisThermodynamic Equilibrium
This contribution presents the thermodynamic and transport properties of a Martian atmosphere gas mixture up to 15 000 K, assuming that the plasma is in local thermodynamic equilibrium. The thermodynamic properties of individual species are computed using a semi-classical statistical mechanics formulation based upon the rigid rotator and harmonic oscillator model. The transport coecients are obtained by means of the perturbative Chapman-Enskog method. The collision integrals are collected from the literature or determined from suitable potential energy curves. Computed thermodynamic and transport properties are compared with numerical results available in the literature. It is found that approximate mixture rules based upon pure species data to compute transport properties are not accurate.
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<i>Molecular Theory of Gases and Liquids</i>
Joseph O. Hirschfelder, C. F. Curtiss, R. Byron Bird · Physics Today · 1955 · 11.4K citations
Natural Sciences, Chemistry, Physics +14
Molecular Theory of Gases and Liquids.
O. K. Rice · Journal of the American Chemical Society · 1955 · 3.9K citations