Chemical and Pharmaceutical Bulletin · 1989 · 26 citations · 0 references
Life SciencesBiochemistryMedicinal ChemistryPlant BiochemistryStructure-activity RelationshipsMedicinal PlantsMetabolite IdentificationTerpenoid BiosynthesisMethylation Analysis Of PolysaccharidesNuclear Magnetic Resonance Data AnalysisPhenylpropanoid GlycosidesPlant Defensive TerpenoidsSaponin BiosynthesisTerpenoid GlycosidesTerpenoid Profiling
The main molluscicidal activity of the methanol extract of Lysimachia sikokiana is due to several triterpenic saponins called sakuraso-saponins. The most active component was isolated from the aerial parts and elucidated as 3-O-beta-xylopyranosyl-(1----2)-beta-glucopyranosyl-(1----4)- [beta-glucopyranosyl-(1----2)]-alpha-arabinopyranosyl protoprimulagenin A, named lysikoianoside 1, on the basis of 1H- and 13C-nuclear magnetic resonance spectral data and methylation analysis results.