Concepedia

Coordination−Insertion Copolymerization of Allyl Monomers with Ethylene

Shingo Ito, Masafumi Kanazawa, Kagehiro Munakata, Jun-Ichi Kuroda, Yoshikuni Okumura, Kyoko Nozaki

Journal of the American Chemical Society · 2011 · 126 citations · 35 references

DOI

Concepts

Abstract

Coordination-insertion copolymerization of allyl monomers with ethylene was developed by using a palladium/phosphine-sulfonate catalyst. A variety of allyl monomers, including allyl acetate, allyl alcohol, protected allylamines, and allyl halides, were copolymerized with ethylene to form highly linear copolymers that possess in-chain -CH(2)CH(CH(2)FG)- units.

References

35

Palladium catalysed copolymerisation of ethene with alkylacrylates: polar comonomer built into the linear polymer chainElectronic supplementary information (ESI) available: NMR data for entries 1, 9, 10, 12 and size exclusion chromatographic data for entries 1, 3, 8, 12. See http://www.rsc.org/suppdata/cc/b1/b111252j/

E. Drent, Rudmer van Dijk, Roel van Ginkel et al. · Chemical Communications · 2002 · 436 citations

, , +18

Insertion Polymerization of Acrylate

Damien Guironnet, Philipp Roesle, Thomas Rünzi et al. · Journal of the American Chemical Society · 2008 · 279 citations · Full text

, , +17

Formation of Linear Copolymers of Ethylene and Acrylonitrile Catalyzed by Phosphine Sulfonate Palladium Complexes

Takuya Kochi, Shusuke Noda, Kenji Yoshimura et al. · Journal of the American Chemical Society · 2007 · 267 citations

, , +15

Copolymerization of Ethylene and Alkyl Vinyl Ethers by a (Phosphine- sulfonate)PdMe Catalyst

Shuji Luo, Javier Vela, G.R. Lief et al. · Journal of the American Chemical Society · 2007 · 234 citations

, , +21

Structural Distribution of Linear Low-Density Polyethylenes

Satoru Hosoda · Polymer Journal · 1988 · 216 citations · Full text

, , +5