Physical Review Letters · 2012 · 83 citations · 22 references
Natural SciencesMaterials EngineeringMaterials ScienceCrystal StructureRheologySolid State PhysicsAtomic PackingClose-packed StructuresCrystalline MaterialsCrystallization ProcessesNucleationCrystal NucleationCyclic Shear StrengthHard-sphere PackingHexagonal Close-packed StructureHexagonal SymmetryParticle Packing FractionParticle Volume Fraction EffectsPolycrystalline Materials
We investigate the nucleation of ordered phases, their symmetries, and distributions in dense frictional hard sphere packings as a function of particle volume fraction ϕ, by imposing cyclic shear and constant applied pressure conditions. We show, with internal imaging, that the nucleating crystallites in the bulk consist of 10-60 spheres with hexagonal close packed (hcp) order and nonspherical shape, that are oriented preferentially along the shear axis. Above ϕ=0.62±0.005, crystallites with face centered cubic (fcc) order are observed with increasing probability, and ordered domains grow rapidly. A polycrystalline phase with domains of fcc and hcp order is observed after hundreds of thousands of shear cycles.
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