Equation of State Beyond the Radius of Convergence of the Virial Expansion

Abstract

The well-known problem of the virial expansion low-density limitation is considered within Mayer's cluster expansion method. The expression for the configuration integral and the corresponding equation of state are presented based on this approach but not limited by the convergence radius of the series for density and activity. When taking into account any number of irreducible integrals at the thermodynamic limit, this equation of state demonstrates the exact coincidence with the virial one inside the domain of its convergence but specifies the condensation process directly outside that domain. Thus, the assumption of some researchers that the condensation should appear in the domain where the proof of the virial expansion is limited may now be regarded as confirmed, exclusively using the classical Gibbs statistics.