Inorganic Chemistry · 2011 · 26 citations · 22 references
Natural SciencesChemistryCrystal StructureInorganic ChemistryPhysical ChemistryCluster ChemistryCluster CompoundsCoordination ChemistryCrystal ChemistryMetal-ligand BondingTransition Metal ComplexesAnion ExchangeBonding In Coordination CompoundsCluster SynthesisComplexation ChemistryCrystalline StructureElectronic Structure Of Metal Complexes
The Zn(6) cluster complex 2 of the trisaloph ligand was synthesized using EtCO(2)(-) anions as bridging ligands. Complex 2 has a dimeric structure in the crystalline state, while two monomeric isomers were in equilibrium in solution. The anion-exchange reaction successfully resulted in nuclearity control from Zn(7) to Zn(6).
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Catalytic Asymmetric Synthesis.
Ryōji Noyori · Journal of Synthetic Organic Chemistry Japan · 1992 · 809 citations · Full text