Thermodynamics of some simple sulfur-containing molecules

Abstract

The t hermodynamic functions ( F o-f1 ~) / T, ( HO -H~) / T, So ( Ho-Tl~) , and C; are calculated to high temperatures for gaseous sulfur (mon atomic and di ato mic) , sulfur monoxide, s ulfur dioxide, sulfur trioxide, and hydroge n sulfide from molecular and spectroscopic data. Values of the heats of formation of the various ato mic and molec uiar species are selected from published experimental data, and certain industrially importa ntequ ilibria are calculated.