Publication | Closed Access
Light induced catalytic hydrodefluorination of perfluoroarenes by porphyrin rhodium
23
Citations
68
References
2016
Year
Rhodium Porphyrin ComplexesChemical EngineeringEngineeringPhotoredox ProcessPhotochemistryMechanistic PhotochemistryPorphyrin RhodiumFluorous SynthesisPhotocatalytic HydrodefluorinationOrganic ChemistryPhotocatalysisHydrodefluorination ProductsCatalysisSynthetic PhotochemistryChemistry
Photocatalytic hydrodefluorination of a series of perfluoroarenes by rhodium porphyrin complexes was described. The key intermediate (por)Rh-C<sub>6</sub>F<sub>4</sub>R underwent fast photo-cleavage of Rh–C bonds to produce hydrodefluorination products.
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