Polyelectrolytes with sulfonic acid groups useful in the synthesis and stabilization of Au and Ag nanoparticles

Abstract

Two novel polyelectrolytes were obtained by chemical modification of poly(4-acryloyloxybenzaldehyde) using o- and p-aminophenylsulfonic acid, the characterization shows a chemical modification of 24.38 and 63.33%, respectively. The study shows that the polyelectrolyte with sulfonic acid in para position reduces metal ions more rapidly than polyelectrolyte in ortho position. The obtained nanoparticles of Au and Ag were characterized by ultraviolet–visible absorption spectroscopy (UV–vis) and transmission electron microscopy. The results showed that these ionic polymers are not only capable of reducing gold and silver ions, but also can stabilize the nanoparticles in the colloidal solutions. With these polymers, the process of metallic ions reduction is very slow and they lead to the production of Au and Ag nanoparticles with quasi-spherical shapes which are stable in colloidal solutions for several months. The advantage of the method used here is that the reduction can be realized in water at room temperature.