One synthesis: two redox states. Temperature-oriented crystallization of a charge transfer {Fe<sub>2</sub>Co<sub>2</sub>} square complex in a {FeIILSCoIIILS}<sub>2</sub> diamagnetic or {FeIIILSCoIIHS}<sub>2</sub> paramagnetic state - Concepedia

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One synthesis: two redox states. Temperature-oriented crystallization of a charge transfer {Fe<sub>2</sub>Co<sub>2</sub>} square complex in a {FeIILSCoIIILS}<sub>2</sub> diamagnetic or {FeIIILSCoIIHS}<sub>2</sub> paramagnetic state

47

Citations

29

References

2016

Year

Siddhartha De, Juan‐Ramón Jiménez, Yanling Li, Lise‐Marie Chamoreau, Alexandrine Flambard, Yves Journaux, Azzedine Bousseksou, Rodrigue Lescouëzec

Magnetic PropertiesEngineeringCharge TransferMagnetic ResonanceChemistryMagnetic MaterialsInorganic CompoundMagnetismQuantum MaterialsMaterials ScienceInorganic ChemistryTemperature-oriented CrystallizationPhysicsMagnetic MaterialCrystallographyInorganic SynthesisQuantum MagnetismFerromagnetismMolecule-based MagnetNatural SciencesCoordination ComplexCondensed Matter PhysicsApplied PhysicsRedox States

Abstract

The reaction of [Fe<sup>III</sup>(Tp)(CN)<sub>3</sub>]<sup>−</sup> with [Co<sup>II</sup>(vbik)<sub>2</sub>(S)<sub>2</sub>]<sup>2+</sup> leads selectively to the crystallization of cyanide-bridged diamagnetic {FeIILSCoIIILS}<sub>2</sub> charge-transfer complexes at 5 °C or paramagnetic {FeIIILSCoIIHS}<sub>2</sub> ones at 35 °C.

References

	Year	Citations

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