Nanoscale · 2016 · 187 citations · 28 references
EngineeringMaterials EngineeringMaterials ScienceNanomaterialsNanotechnologySensorsGas SensorsInorganic NanoparticlesMetal Oxide NanomaterialsMetal OxidesNanosensorsSensor MaterialsExfoliationGas Sensor Response TimeNanosheetsNanostructured Gas SensorsNanostructured OxidesRecovery TimeSensor Response TimeSurface Area
By taking advantages of both grinding and sonication, an effective exfoliation process is developed to prepare two-dimensional (2D) molybdenum oxide (MoO3) nanosheets. The approach avoids high-boiling-point solvents that would leave a residue and cause aggregation. Gas sensors fabricated using the 2D-MoO3 nanosheets provide a significantly enhanced chemical sensor performance. Compared with the sensors using bulk MoO3, the response of the 2D-MoO3 sensor increases from 7 to 33; the sensor response time is reduced from 27 to 21 seconds, and the recovery time is shortened from 26 to 10 seconds. We attribute the superior performance to the 2D-structure with a much increased surface area and reactive sites.
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Branimir Radisavljevic, Jacopo Brivio, Valentina Giacometti et al. · Nature Nanotechnology · 2011 · 14.8K citations · Full text
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Natural Sciences, Materials Engineering, Materials Science +17