Publication | Closed Access
A theoretical insight into atmospheric chemistry of HFE-7100 and perfluoro-butyl formate: reactions with OH radicals and Cl atoms and the fate of alkoxy radicals
23
Citations
37
References
2016
Year
Chemical KineticsRadical EmissionEngineeringAtmospheric LifetimeOrganic ChemistryChemistryCalculated Rate ConstantsChemical EngineeringTheoretical InsightThermodynamicsPhysicsRadical (Chemistry)Global Warming PotentialFluorous SynthesisHydrogenEnergyHydrogen TransitionAlkoxy RadicalsNatural SciencesHalogenationChemical Thermodynamics
The calculated rate constants for C<sub>4</sub>F<sub>9</sub>OCH<sub>3</sub> + OH/Cl reactions are found to be 1.94 × 10<sup>−14</sup> and 1.74 × 10<sup>−12</sup> cm<sup>3</sup> molecule<sup>−1</sup> s<sup>−1</sup>, respectively, at 298 K. The atmospheric lifetime and global warming potential for HFE-7100 are computed to be 2.12 years and 155.3, respectively.
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