The Journal of Physical Chemistry Letters · 2015 · 243 citations · 60 references
Natural SciencesChemistryMaterials ScienceElectrochemistryEnergy MaterialsInorganic ChemistryAnode MaterialsBattery Cell ChemistryBattery MaterialsElectrochemical Energy StorageElectrode MaterialsElectrolyte MaterialsAnode BehaviorAnode DesignAnode PerformanceDendrite FormationDendrite GrowthLithium-metal AnodesLithium-metal BatteriesMagnesium-ion Batteries
Magnesium is an ideal metal anode that has nearly double the volumetric capacity of lithium metal with a very negative reduction potential of -2.37 vs SHE. A significant advantage of magnesium is the apparent lack of dendrite formation during charging, which overcomes major safety and performance challenges encountered with using lithium metal anodes. Here, we highlight major recent advances in nonaqueous Mg electrochemistry, notably the development of electrolytes and cathodes, and discuss some of the challenges that must be overcome to realize a practical magnesium battery.
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