Use of Dialkyldithiocarbamato Complexes of Bismuth(III) for the Preparation of Nano- and Microsized Bi₂S₃ Particles and the X-ray Crystal Structures of [Bi{S₂CN(CH₃)(C₆H₁₃)}₃] and [Bi{S₂CN(CH₃)(C₆H₁₃)}₃(C₁₂H₈N₂)]

Abstract

A range of bismuth(III) dithiocarbamato complexes were prepared and characterized. The X-ray crystal structures of the compounds [Bi{S2CN(CH3)(C6H13)}3] (1) and [Bi{S2CN(CH3)(C6H13)}3(C12H8N2)] (2) are reported. The preparation of Bi2S3 particulates using a wet chemical method and involving the thermalysis of Bi(III) dialkyldithiocarbamato complexes is described. The influence of several experimental parameters on the optical and morphological properties of the Bi2S3 powders was investigated. Nanosized Bi2S3 colloids were obtained having long-term stability and showing a blue shift on the optical band edge; the presence of particles exhibiting quantum size effects is discussed. Morphological well-defined Bi2S3 particles were obtained in which the fiber-type morphology is prevalent.