Synthesis of a new family of ionophores based on aluminum–dipyrrin complexes (ALDIPYs) and their strong recognition of alkaline earth ions

Abstract

Mononuclear and dinuclear aluminum-dipyrrin complexes (ALDIPYs) were synthesized as a new family of ionophores. They exhibited colorimetric and fluorometric responses to alkaline earth ions in an aqueous mixed solvent. The strong recognition was achieved via multipoint interactions with the oxygen atoms appropriately incorporated into the ligand framework.