(Boratabenzene)(cyclooctatetraenyl) lanthanide complexes: a new type of organometallic single-ion magnet

Yin‐Shan Meng, Chunhong Wang, Yi‐Quan Zhang, Xuebing Leng, Bing‐Wu Wang, Yaofeng Chen, Song Gao

Inorganic Chemistry Frontiers · 2016 · 100 citations · 58 references

Concepts

Abstract

(Boratabenzene)(cyclooctatetraenyl) lanthanide complexes were synthesized, and the erbium ones showed single-ion magnet behaviours. One complex exhibited hysteresis up to 8 K, and another one featured energy barrier of 300 cm<sup>−1</sup>.

References

58