European Journal of Inorganic Chemistry · 2016 · 32 citations · 35 references
Natural SciencesChemistryInorganic ChemistryOrganometallic ChemistrySolid-state ChemistryCoordination ChemistryInorganic SynthesisLigand BindingMetal-ligand BondingTransition Metal ChemistryTransition Metal ComplexesChelation StudiesComplexation ChemistryIntermolecular Metal-ligand InteractionsLigand DesignLigand Effects On ReactivitySmall Molecule ActivationTransition Metal-catalyzed SynthesisTransition-metal-catalyzed Functionalization
Dinitrogen complexes of the first row transition metals Cr–Co supported by 2 nd generation hydrotris(pyrazolyl)borate (Tp R,R′ ) ligands were characterized by structure and reactivity. Compounds of the type (Tp R,R′ M) n (N 2 ) ( n = 1,2) were prepared and evaluated as precursors for small molecule activation, with specific application to reactions of O 2 .
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