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Unexpected Formation of the Novel Pentanuclear Heterodimetallic Metallamacrocycle {<i>p</i>-[(CO)<sub>3</sub>MoC<sub>5</sub>H<sub>4</sub>C(O)]<sub>2</sub>C<sub>6</sub>H<sub>4</sub>}Ph<sub>4</sub>Sn<sub>3</sub>S<sub>3</sub>
10
Citations
20
References
2002
Year
Inorganic ChemistryChemical EngineeringUnexpected FormationEngineeringCyclic Sn3s3 SystemCoordination ComplexMolecular ComplexChemistryHeterocycle ChemistryPhsncl3 YieldsInorganic SynthesisComplex 1Inorganic Compound
Reaction of the dianion {p-[(CO)3MoC5H4C(O)]2C6H4}2- with PhSnCl3 yields the tetranuclear heterodimetallic complex p-[(PhCl2Sn)(CO)3MoC5H4C(O)]2C6H4 (1). Treatment of complex 1 with Na2S·9H2O in boiling ethanol results in the novel pentanuclear heterodimetallic metallamacrocyclic complex {p-[(CO)3MoC5H4C(O)]2C6H4}Ph4Sn3S3 (2), which fuses a cyclic Sn3S3 system.
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