Stereoselective Synthesis of <i>P</i>‐Stereogenic <i>N</i>‐Phosphinyl Compounds

Abstract

Abstract A number of P ‐stereogenic N ‐phosphinyl compounds were stereoselectively prepared in good yields by a straightforward approach, thanks to the diversified and, up until now, unexplored reactivity of ( R )‐ and ( S )‐dicyclohexylidene‐ D ‐glucose methyl phenyl phosphinates toward metal amides. Under adequate conditions, structurally different phosphinamides with one or two P ‐chiral centers were obtained.