Concepedia

Synthesis of 1,1-diboronate esters by cobalt-catalyzed sequential hydroboration of terminal alkynes

Ziqing Zuo, Zheng Huang

Organic Chemistry Frontiers · 2016 · 111 citations · 71 references

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Concepts

Abstract

Co-catalyzed sequential hydroborations of alkyl and aryl alkynes with pinacolborane produce 1,1-diboronate esters with high selectivity and yields.

References

71

Enantioselective preparation and chemoselective cross-coupling of 1,1-diboron compounds

Jack Chang Hung Lee, Robert McDonald, Dennis G. Hall · Nature Chemistry · 2011 · 433 citations

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Alkylboronic Esters from Copper‐Catalyzed Borylation of Primary and Secondary Alkyl Halides and Pseudohalides

Chu‐Ting Yang, Zhen‐Qi Zhang, Hazmi Tajuddin et al. · Angewandte Chemie International Edition · 2011 · 416 citations · Full text

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Cross Coupling Reactions of Chiral Secondary Organoboronic Esters With Retention of Configuration

Daisuke Imao, Ben W. Glasspoole, Véronique S. Laberge et al. · Journal of the American Chemical Society · 2009 · 373 citations

, , +9

Rhodium- or Iridium-Catalyzed <i>trans</i>-Hydroboration of Terminal Alkynes, Giving (<i>Z</i>)-1-Alkenylboron Compounds

Toshimichi Ohmura, Yasunori Yamamoto, Norio Miyaura · Journal of the American Chemical Society · 2000 · 353 citations

, , +9

Mild and stereoselective hydroborations of functionalized alkynes and alkenes using pinacolborane

Charles E. Tucker, Jessica Davidson, Paul Knochel · The Journal of Organic Chemistry · 1992 · 338 citations

, , +8