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Enzyme-Dependent [4 + 2] Cycloaddition Depends on Lid-like Interaction of the N-Terminal Sequence with the Catalytic Core in PyrI4

BiosynthesisEngineeringBiochemistryNatural SciencesBiocatalysisEnzyme CatalysisLid-like InteractionMolecular BiologyCatalytic CoreCatalysisMolecular CatalysisN-terminal SequenceChemical BiologyStructure-function Enzyme Kinetics