High Reversible Lithium Storage Capacity and Structural Changes of Fe₂O₃ Nanoparticles Confined inside Carbon Nanotubes

Abstract

The structural evolution of electrochemically prelithiated Fe 2 O 3 nanoparticles confined in carbon nanotubes (CNTs) during lithium insertion/extraction is studied by in situ transmission electron microscopy. It is found that the aggregation and coarsening of Fe core‐containing Li 2 O (Fe@Li 2 O) nanograins formed during the charge process are prevented by the spatial restriction of the CNTs. A high reversible capacity of 2071 mA h g −1 for the encapsulated Fe 2 O 3 nanoparticles in CNTs is demonstrated when the material is used as the anode of lithium ion batteries. This is the highest reversible capacity ever reported for an Fe 2 O 3 electrode. The significantly improved lithium storage capacity of the Fe 2 O 3 nanoparticles is attributed to the extra lithium storage due to the enhanced interfacial lithium storage and reversible reaction of LiOH to form LiH and solid‐electrolyte‐interphase conversion originating from the nanoconfinement of CNTs as well as the very small particle size of the Fe@Li 2 O nanograins and their good electrical contact with CNTs.