Physical review. E · 2016 · 20 citations · 33 references
Natural SciencesPhysicsCondensed Matter PhysicsProbability TheoryStochastic ProcessesBrownian MotionStatistical MechanicsTime-dependent TransportClose PackingDiffusive TransportDiffusivityFluctuation TheoryGas Density DistributionGas DiffusivityGas-particle InteractionsInteracting Particle Systems
Suppose that a d-dimensional domain is filled with a gas of (in general, interacting) diffusive particles with density n_{0}. A particle is absorbed whenever it reaches the domain boundary. Employing macroscopic fluctuation theory, we evaluate the probability P that no particles are absorbed during a long time T. We argue that the most likely gas density profile, conditional on this event, is stationary throughout most of the time T. As a result, P decays exponentially with T for a whole class of interacting diffusive gases in any dimension. For d=1 the stationary gas density profile and P can be found analytically. In higher dimensions we focus on the simple symmetric exclusion process (SSEP) and show that -lnP≃D_{0}TL^{d-2}s(n_{0}), where D_{0} is the gas diffusivity, and L is the linear size of the system. We calculate the rescaled action s(n_{0}) for d=1, for rectangular domains in d=2, and for spherical domains. Near close packing of the SSEP s(n_{0}) can be found analytically for domains of any shape and in any dimension.
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