Introducing Dimensionality to the Archetypical Mn<sub>12</sub> Single-Molecule Magnet: a Family of [Mn<sub>12</sub>]<sub><i>n</i></sub> Chains - Concepedia

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Introducing Dimensionality to the Archetypical Mn<sub>12</sub> Single-Molecule Magnet: a Family of [Mn<sub>12</sub>]<sub><i>n</i></sub> Chains

16

Citations

16

References

2016

Year

Sergio A. Corrales, John M. Cain, Kelley A. Uhlig, Andrew M. Mowson, Constantina Papatriantafyllopoulou, Marcus K. Peprah, Andrew Ozarowski, Anastasios J. Tasiopoulos, George Christou, Mark W. Meisel,

Inorganic Chemistry

Magnetic PropertiesEngineeringLow-dimensional MagnetismMagnetic ResonanceMolecular BiologyOne-dimensional MagnetismChemistryMagnetic MaterialsWell-studied Single-molecule MagnetsMagnetismQuantum MaterialsMicromagneticsMolecular MagnetismInorganic ChemistryPhysicsLow-dimensional SystemsMagnetic MaterialCrystallographyQuantum MagnetismSpintronicsFerromagnetismMolecule-based MagnetNatural SciencesCondensed Matter PhysicsApplied PhysicsCluster ChemistryMagnetic PropertyMolecule-based MaterialChain Structures

Abstract

The [Mn12O12(O2CR)16(L4)] family (R = various; L = terminal ligand) of clusters holds a special place in molecular magnetism; they are the most well-studied single-molecule magnets (SMMs). Targeted linkage of these SMMs has now been achieved for the first time. The resulting chain structures have been confirmed crystallographically, and the magnetic properties, up to 1.14 GPa, and high-field electron paramagnetic resonance spectra have been collected and analyzed.

References

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