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Selective Synthesis of Sulfoxides through Oxidation of Sulfides with Sodium Hypochlorite Pentahydrate Crystals
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2015
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High YieldsInorganic ChemistryChemical EngineeringEngineeringAqueous Acetonitrile SolutionCorresponding SulfoxidesOrganic ChemistryCatalysisHomogeneous CatalysisChemistrySynthesis MethodDesulfurizationSelective SynthesisDeoxygenationInorganic SynthesisCatalytic Synthesis
Oxidation of sulfides with sodium hypochlorite pentahydrate crystals (1.1 equiv) in an aqueous acetonitrile solution selectively produces the corresponding sulfoxides in high yields. This procedure is catalyst-free and environmentally benign.