Contact glow discharge electrolysis: its origin, plasma diagnostics and non-faradaic chemical effects

Abstract

Contact glow discharge electrolysis (CGDE) also termed plasma electrolysis is a novel electrolysis where a stable sheath of light emitting plasma develops around an electrode immersed well inside a relatively high-conductivity liquid electrolyte during normal electrolysis (NE) at several hundred volts. The phenomenon may develop in dc-, pulsed dc-, ac- as well as RF-driven electrolyses. The chemical effects of CGDE are remarkably non-faradaic in respect to the nature of the products as well as their yields. The article traces comprehensively the progress made in studies of CGDE in aqueous and non-aqueous solutions since 1844 and reviews the developments in the understanding of its origin, light emission, plasma state and non-faradaic effects leading to the elucidation of detailed mechanism of the origin of CGDE on the basis of the onset of hydrodynamic instabilities in local vaporization of the solvent near the working electrode during NE, and that of highly non-faradaic effects of CGDE based on a model of two reaction zones located within the electrode plasma and at the plasma–liquid interface producing solvent derived radicals at high local concentrations. Keeping in view the recent surge of interest in varied applications of CGDE, the article is appended with highlights of these applications across synthetic chemistry, waste water treatment, electrosurgical devices, nanoparticle fabrications, surface engineering and micro-machining.