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Enantioselective hydrogenation of ketones by iridium nanoparticles ligated with chiral secondary phosphine oxides
46
Citations
95
References
2016
Year
Inorganic ChemistryChemical EngineeringEnantioselective SynthesisEngineeringSupramolecular AssemblyIridium NanoparticlesChiral Iridium NanoparticlesCatalysisOrganometallic CatalysisHydrogenChemistryAsymmetric CatalysisEnantioselective HydrogenationCatalytic Synthesis
Chiral iridium nanoparticles (<bold>IrNPs</bold>) were synthesized by H<sub>2</sub>reduction of (1,5-cyclooctadiene)(methoxy)iridium(<sc>i</sc>) dimer ([Ir(OMe)(COD)]<sub>2</sub>) in the presence of an asymmetric secondary phosphine oxide.
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