Quantum Dot Luminescent Concentrator Cavity Exhibiting 30-fold Concentration

Noah D. Bronstein, Yuan Yao, Lu Xu, Erin O’Brien, Alexander S. Powers, Vivian E. Ferry, A. Paul Alivisatos, Ralph G. Nuzzo

ACS Photonics · 2015 · 136 citations · 29 references

DOIFull text

Open access

Concepts

Abstract

High Resolution Image Download MS PowerPoint Slide Luminescent solar concentrators doped with CdSe/CdS quantum dots provide a potentially low-cost and high-performance alternative to costly high-band-gap III–V semiconductor materials to serve as a top junction in multijunction photovoltaic devices for efficient utilization of blue photons. In this study, a photonic mirror was coupled with such a luminescent waveguide to form an optical cavity where emitted luminescence was trapped omnidirectionally. By mitigating escape cone and scattering losses, 82% of luminesced photons travel the length of the waveguide, creating a concentration ratio of 30.3 for blue photons in a waveguide with a geometric gain of 61. Further, we study the photon transport inside the luminescent waveguide, showing unimpeded photon collection across the entire length of the waveguide.

References

29