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Alkaline-Earth-Catalyzed sp3 C–H Functionalization of Methyl Azaarenes and Its Use in a One-Pot Four-Component Synthesis of Azaarenyl Benzylpyrazolones
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2015
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Chemical EngineeringMethyl AzaarenesCalcium TriflateEngineeringOne-pot Four-component SynthesisNovel OrganocatalystsAzaarenyl BenzylpyrazolonesOrganic ChemistryCatalysisChemistryHeterocycle ChemistrySynthetic ChemistryOne-pot Four-component Reaction
The sp<sup>3</sup> C–H functionalization of methyl azaarenes by using calcium triflate as the catalyst is described, together with its use in the first synthesis of azaarenyl benzylpyrazolones by a one-pot four-component reaction.