Enhanced Thermoelectric Performance of Nanostructured Bi₂Te₃ through Significant Phonon Scattering

Abstract

N-type Bi2Te3 nanostructures were synthesized using a solvothermal method and in turn sintered using sparking plasma sintering. The sintered n-type Bi2Te3 pellets reserved nanosized grains and showed an ultralow lattice thermal conductivity (∼0.2 W m(-1) K(-1)), which benefits from high-density small-angle grain boundaries accommodated by dislocations. Such a high phonon scattering leads an enhanced ZT of 0.88 at 400 K. This study provides an efficient method to enhance thermoelectric performance of thermoelectric nanomaterials through nanostructure engineering, making the as-prepared n-type nanostructured Bi2Te3 as a promising candidate for room-temperature thermoelectric power generation and Peltier cooling.