Angewandte Chemie International Edition · 2015 · 868 citations · 36 references
Natural SciencesChemical EngineeringMaterials ScienceCatalysisEnergy MaterialsMaterials ChemistryCatalytic MaterialsElectrochemical CellsElectrode MaterialsFuel CellsNanostructured Energy MaterialsRedox-active MaterialsBifunctional CatalysisBifunctional CatalystsGraphene OxideHydrogen EvolutionOxygen Reduction CatalystsPorous CarbonWater SplittingZinc-air Batteries
The high cost and scarcity of noble metal catalysts, such as Pt, have hindered the hydrogen production from electrochemical water splitting, the oxygen reduction in fuel cells and batteries. Herein, we developed a simple template-free approach to three-dimensional porous carbon networks codoped with nitrogen and phosphorus by pyrolysis of a supermolecular aggregate of self-assembled melamine, phytic acid, and graphene oxide (MPSA/GO). The pyrolyzed MPSA/GO acted as the first metal-free bifunctional catalyst with high activities for both oxygen reduction and hydrogen evolution. Zn-air batteries with the pyrolyzed MPSA/GO air electrode showed a high peak power density (310 W g(-1) ) and an excellent durability. Thus, the pyrolyzed MPSA/GO is a promising bifunctional catalyst for renewable energy technologies, particularly regenerative fuel cells.
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Metal-free efficient photocatalyst for stable visible water splitting via a two-electron pathway
Juan Liu, Yang Liu, Naiyun Liu et al. · Science · 2015 · 4.4K citations