Mathematical Modeling of the Lithium, Thionyl Chloride Static Cell: II . Acid Electrolyte

Abstract

A mathematical model for a complete static cell with acid electrolyte is presented. Concentrated solution theory is extended to account for the presence of two neutral species in the electrolyte. The effects of initial acid concentration, positive electrode thickness, and galvanostatic discharge rate on cell performance are elucidated. Results are compared with equivalent cells that use a neutral electrolyte.