Performance Evaluation of Polybenzimidazole Under High-Energy Radiation Environment

Abstract

Polybenzimidazole is a recently emerged high-performance polymer exhibiting excellent thermal and mechanical properties. Because of the nature of the chemical structure of polybenzimidazole, it has great potential to be used as high-temperature radiation-resistant material for applications in space environment. In this context, a study is performed to evaluate the thermal, mechanical, and optical performance of polybenzimidazole after exposure to high-energy electron and gamma radiation. Polybenzimidazole films are exposed to gamma radiation and electron radiation for a dose of 300 and 1000 kGy, respectively. Thermal gravimetric analysis shows that exposure of polybenzimidazole to high-energy radiation has not deteriorated the thermal stability of the polymer, and it has maintained its thermal stability even up to a temperature of 500°C with a total weight loss of 15%. Dynamic mechanical analysis shows that the exposure of polybenzimidazole to high-energy radiation has even improved the storage modulus in the high-temperature range. Tensile test results indicate that high-energy radiation has a very minor effect on the tensile strength of polybenzimidazole. However, a decrease in tensile strain is observed. Photospectroscopic results show that polybenzimidazole has not changed its light-transmitting characteristic even after exposure to high-energy radiation. All these results indicate that polybenzimidazole has great potential for application in space and nuclear industry.