Concepedia

Enantioselective dearomative [3 + 2] cycloadditions of indoles with azomethine ylides derived from alanine imino esters

Anthony L. Gerten, Levi M. Stanley

Organic Chemistry Frontiers · 2016 · 86 citations · 26 references

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Concepts

Abstract

Dearomative cycloadditions of imino esters derived from alanine with 3-nitroindoles form<italic>exo</italic>′-pyrroloindolines in good yields with high diastereo- and enantioselectivities.

References

26

Catalytic Asymmetric Dearomatization Reactions

Chun‐Xiang Zhuo, Wei Zhang, Shu‐Li You · Angewandte Chemie International Edition · 2012 · 1.3K citations

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Tandem Au-Catalyzed 3,3-Rearrangement−[2 + 2] Cycloadditions of Propargylic Esters:  Expeditious Access to Highly Functionalized 2,3-Indoline-Fused Cyclobutanes

Liming Zhang · Journal of the American Chemical Society · 2005 · 450 citations

Copper-Catalyzed Highly Enantioselective Cyclopentannulation of Indoles with Donor–Acceptor Cyclopropanes

Xiong Hu, Hao Xu, Saihu Liao et al. · Journal of the American Chemical Society · 2013 · 354 citations

Intramolecular Dearomatizing [3 + 2] Annulation of α-Imino Carbenoids with Aryl Rings Furnishing 3,4-Fused Indole Skeletons

Tomoya Miura, Yuuta Funakoshi, Masahiro Murakami · Journal of the American Chemical Society · 2014 · 224 citations

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Enantioselective Synthesis of Pyrroloindolines by a Formal [3 + 2] Cycloaddition Reaction

Lindsay M. Repka, Jane Ni, Sarah E. Reisman · Journal of the American Chemical Society · 2010 · 216 citations

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