MILD OXIDATION OF CELLULOSE FIBERS USING DIOXYGEN AS ULTIMATE OXIDIZING AGENT

Gabriela Biliuță, Lidija Fras, Valeria Harabagiu, Sergiu Coseri, Grigore Ghica

University of Maribor digital library (University of Maribor) · 2011 · 20 citations · 0 references

Full text

Open access

Concepts

Abstract

Two types of regenerate cellulose fibres were oxidized under mild conditions, by using Nhydroxyphthalimide as catalyst and molecular oxygen as ultimate oxidizing agent. The amounts of negatively charged groups introduced were determined by means of potentiometric titration. The degree of polymerization and molar mass of the oxidized fibres determined viscosimetrically, has been found to be almost unaffected during oxidation.