Concepedia

Double carboxylation of o-alkynyl acetophenone with carbon dioxide

Wen‐Zhen Zhang, Mingwang Yang, Xu‐Tong Yang, Ling‐Long Shi, Huibo Wang, Xiao‐Bing Lu

Organic Chemistry Frontiers · 2015 · 45 citations · 97 references

DOI

Concepts

Abstract

A copper-catalyzed double carboxylation of <italic>o</italic>-alkynyl acetophenone using carbon dioxide <italic>via</italic> a carboxylation/intramolecular cyclization/second carboxylation sequence to afford 1(3<italic>H</italic>)-isobenzofuranylidene dicarboxylic esters in good yields is developed.

References

97

Using carbon dioxide as a building block in organic synthesis

Qiang Liu, Lipeng Wu, Ralf Jackstell et al. · Nature Communications · 2015 · 2.1K citations · Full text

, , +16

Transition Metal-Catalyzed/Mediated Reaction of Allenes with a Nucleophilic Functionality Connected to the α-Carbon Atom

Shengming Ma · Accounts of Chemical Research · 2003 · 627 citations

, , +9

Conversion of Carbon Dioxide into Methanol with Silanes over N‐Heterocyclic Carbene Catalysts

Siti Nurhanna Riduan, Yugen Zhang, Jackie Y. Ying · Angewandte Chemie International Edition · 2009 · 593 citations · Full text

, , +15

Recent developments in carbon dioxide utilization under mild conditions

Siti Nurhanna Riduan, Yugen Zhang · Dalton Transactions · 2010 · 579 citations

, , +13

A Diagonal Approach to Chemical Recycling of Carbon Dioxide: Organocatalytic Transformation for the Reductive Functionalization of CO<sub>2</sub>

Christophe Das Neves Gomes, Olivier Jacquet, Claude Villiers et al. · Angewandte Chemie International Edition · 2011 · 552 citations · Full text

, , +11