Concepedia

A novel route to the fluorinated diimines: carbon monoxide-promoted reductive homocoupling of fluorinated imidoyl iodides in the presence of a palladium catalyst

Hideki Amii, Mitsuhiro Kohda, Motoharu Seo, Kenji Uneyama

Chemical Communications · 2003 · 29 citations · 25 references

DOI

Concepts

Abstract

A new catalytic access to the fluorinated diimines which involves palladium(0)-catalyzed reductive dimerization of the imidoyl iodides is presented.

References

25

Mechanistic Studies of Pd(II)−α-Diimine-Catalyzed Olefin Polymerizations<sup>1</sup>

Daniel J. Tempel, Lynda K. Johnson, R. Leigh Huff et al. · Journal of the American Chemical Society · 2000 · 601 citations

, , +16

One-pot synthesis of trifluoroacetimidoyl halides

Kenji Tamura, Hiromichi Mizukami, Kazuhiro Maeda et al. · The Journal of Organic Chemistry · 1993 · 278 citations

, , +5

Selective Homogeneous Palladium(0)-Catalyzed Hydrogenation of Alkynes to (Z)-Alkenes

Martijn W. van Laren, Cornelis J. Elsevier · Angewandte Chemie International Edition · 1999 · 248 citations

, , +14

Convenient and Efficient Suzuki−Miyaura Cross-Coupling Catalyzed by a Palladium/Diazabutadiene System

Gabriela A. Grasa, Anna C. Hillier, Steven P. Nolan · Organic Letters · 2001 · 247 citations

, , +13

A Novel Example of Chiral Counteranion Induced Enantioselective Metal Catalysis:  The Importance of Ion-Pairing in Copper-Catalyzed Olefin Aziridination and Cyclopropanation

David B. Llewellyn, Dan Adamson, Bruce A. Arndtsen · Organic Letters · 2000 · 180 citations

, , +16