Concepedia

Jahn–Teller effects in Au<sub>25</sub>(SR)<sub>18</sub>

Marcus A. Tofanelli, Kirsi Salorinne, Thomas W. Ni, Sami Malola, Billy D. Phillips, Hannu Häkkinen, Christopher J. Ackerson

Chemical Science · 2015 · 191 citations · 33 references

DOIFull text

Open access

Concepts

Abstract

in the three oxidation states. In aggregate the data suggests a first-order Jahn-Teller distortion in this compound. The high quality single crystal X-ray structure enables an analysis of the ligand-ligand and ligand-cluster packing interactions that underlie single-crystal formation in thiolate protected metal clusters.

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