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An efficient route for the stereoselective conversion of ketones into three-carbons homologated primary E-allylamines: The palladium-catalysed reaction of vinyl triflates with N,N-di-tert-butoxycarbonyl-N-allylamine.

Cross-coupling ReactionEngineeringVinyl TriflatesStereoselective ConversionOrganic ChemistryCatalysisStereoselective SynthesisChemistryPrimary E-allylaminesAsymmetric CatalysisEnantioselective SynthesisBiomolecular Engineering