Angewandte Chemie International Edition · 2015 · 88 citations · 35 references
Natural SciencesChemistryMaterials ScienceCrystal StructureInorganic ChemistrySolid-state ChemistryCluster ChemistryCluster CompoundsCoordination ChemistryCoordination PolymersCrystal ChemistryMetal-ligand BondingCluster GeometryCluster SynthesisCoordination Polymer SynthesisLigand-stabilized ClustersMetal-ligand Coordination PolymersNoble Metal ClustersSupramolecular Coordination ChemistrySupramolecular Coordination Complexes
The n-butylphosphonate ligand has been employed to construct three new silver(I) thiolate compounds. Single-crystal X-ray analysis revealed that complexes 1 and 2 are Ag48 and Ag51 coordination chain polymers, while 3 contains a discrete Ag48 cluster, in which three different kinds of silver(I) thiolate cluster shells enclose three different phosphonate-functionalized silver(I) cluster cores, respectively. The structures of clusters in 1-3 feature three three-shell arrangements, S@Ag12 @(nBuPO3 )9 @Ag36 S23 , S@Ag11 @(nBuPO3 )7 (MoO4 )2 @Ag40 S27 and MoO4 @Ag12 @(nBuPO3 )8 S6 @Ag36 S24 , respectively.
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All-thiol-stabilized Ag44 and Au12Ag32 nanoparticles with single-crystal structures
Huayan Yang, Yu Wang, Hua-Qi Huang et al. · Nature Communications · 2013 · 779 citations · Full text