Concepedia

cis-Stereoselective nickel-catalyzed cyclization/alkylation and arylation reactions of allenyl-aldehydes and -ketones with organozinc reagentsElectronic supplementary information (ESI) available: typical procedures, NMR-data, and X-ray data. See http://www.rsc.org/suppdata/cc/b2/b207620a/

Suk‐Ku Kang, Seok‐Keun Yoon

Chemical Communications · 2002 · 42 citations · 18 references

DOI

Concepts

Abstract

Highly stereoselective alkylative and arylative cyclization reactions of allenyl-aldehydes and -ketones with organozinc reagents occur efficiently in the presence of catalytic Ni(COD)2 to afford cis-fused homoallylic cyclopentanols.

References

18

Nickel-Catalyzed Cyclizations, Couplings, and Cycloadditions Involving Three Reactive Components

John Montgomery · Accounts of Chemical Research · 2000 · 346 citations

, , +10

A New Stereoselective Method for the Preparation of Allylic Alcohols

Eric Oblinger, John Montgomery · Journal of the American Chemical Society · 1997 · 265 citations

, , +12

Novel Stereoselective Cyclization via .pi.-Allylnickel Complex Generated from 1,3-Diene and Hydride Nickel Complex

Yoshihiro Sato, Masanori Takimoto, Kôji Hayashi et al. · Journal of the American Chemical Society · 1994 · 148 citations

, , +11

Ruthenium-Catalyzed Cycloisomerizations of 1,6- and 1,7-Enynes

Barry M. Trost, F. Dean Toste · Journal of the American Chemical Society · 2000 · 145 citations

, , +9

Reductive Cyclization of Enones by a Titanium Catalyst

Natasha M. Kablaoui, Stephen L. Buchwald · Journal of the American Chemical Society · 1995 · 108 citations

, , +12