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The first total synthesis of (±)-annosqualine by means of oxidative enamide–phenol coupling: pronounced effect of phenoxide formation on the phenol oxidation mechanism

EngineeringBiochemistryPhenol Oxidation MechanismOrganic ChemistryOxidative Enamide–phenol CouplingPharmacologyPhenoxide FormationSynthetic ChemistryBiomolecular EngineeringNatural Product Synthesis