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Re(CO)<sub>5</sub>Br-Catalyzed Coupling of Epoxides with CO<sub>2</sub> Affording Cyclic Carbonates under Solvent-Free Conditions
101
Citations
13
References
2004
Year
Materials ScienceChemical EngineeringOrganic SolventEngineeringCatalytic AmountOrganic ChemistrySolvent-free ConditionsOrganometallic CatalysisCatalysisHomogeneous CatalysisChemistryCatalyst PreparationMolecular CatalysisCatalytic SynthesisCyclic CarbonatesSupercritical Co2
In the presence of a catalytic amount of Re(CO)(5)Br, the coupling of epoxides with supercritical CO(2) without an organic solvent at 110 degrees C has afforded cyclic carbonates in good to excellent yields.
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