Concepedia

Rh(<scp>iii</scp>)-catalyzed redox-neutral annulation of azo and diazo compounds: one-step access to cinnolines

Peng Sun, Youzhi Wu, Yue Huang, Jinyi Xu, Hequan Yao, Aijun Lin

Organic Chemistry Frontiers · 2015 · 63 citations · 48 references

DOI

Concepts

Abstract

Cinnolines were synthesized in one step from azo and diazo compounds <italic>via</italic> a Rh(<sc>iii</sc>)-catalyzed redox-neutral C–H activation and C–N bond formation strategy.

References

48

A Coupling of Benzamides and Donor/Acceptor Diazo Compounds To Form γ-Lactams via Rh(III)-Catalyzed C–H Activation

Todd K. Hyster, Kyle E. Ruhl, Tomislav Rovis · Journal of the American Chemical Society · 2013 · 488 citations

, , +11

Rh-Catalyzed Intermolecular Carbenoid Functionalization of Aromatic C–H Bonds by α-Diazomalonates

Wai-Wing Chan, Siu-Fung Lo, Zhongyuan Zhou et al. · Journal of the American Chemical Society · 2012 · 478 citations

, , +14

Rh(III)-Catalyzed Synthesis of Multisubstituted Isoquinoline and Pyridine <i>N</i>-Oxides from Oximes and Diazo Compounds

Zhuangzhi Shi, Dennis C. Koester, Melissa Boultadakis‐Arapinis et al. · Journal of the American Chemical Society · 2013 · 447 citations

, , +16

Highly Site-Selective Direct C–H Bond Functionalization of Phenols with α-Aryl-α-diazoacetates and Diazooxindoles via Gold Catalysis

Zhunzhun Yu, Ben Ma, Mingjin Chen et al. · Journal of the American Chemical Society · 2014 · 445 citations

, , +16

Rhodium-Catalyzed C–H Activation of Phenacyl Ammonium Salts Assisted by an Oxidizing C–N Bond: A Combination of Experimental and Theoretical Studies

Songjie Yu, Song Liu, Yu Lan et al. · Journal of the American Chemical Society · 2015 · 332 citations

, , +16