Concepedia

Changes in the S<sub>N</sub>Ar reaction mechanism brought about by preferential solvation

Jazmín Alarcón‐Espósito, Ricardo A. Tapia, Renato Contreras, Paola R. Campodónico

RSC Advances · 2015 · 23 citations · 31 references

DOIFull text

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Concepts

Abstract

For model S<sub>N</sub>Ar reactions in mixtures of acetonitrile and water, we found preferential solvation in favor of the aqueous phase.

References

31

Electric Moments of Molecules in Liquids

Lars Onsager · Journal of the American Chemical Society · 1936 · 5.3K citations

, , +8

Theory of Solutions of Molecules Containing Widely Separated Charges with Special Application to Zwitterions

John G. Kirkwood · The Journal of Chemical Physics · 1934 · 1.5K citations

, , +16

Chemical Kinetics and Dynamics

Ilya Prigogine · Annals of the New York Academy of Sciences · 2003 · 912 citations

, , +17

Optimized δ expansion for relativistic nuclear models

G. Krein, R.S. Marques de Carvalho, Débora P. Menezes et al. · The European Physical Journal A · 1998 · 651 citations · Full text

, , +3

Theoretical aspects of physical organic chemistry : the S[N]2 mechanism

Sason Shaik, H. Bernhard Schlegel, Saul Wolfe · Medical Entomology and Zoology · 1992 · 299 citations

, , +17