Concepedia

Direct enantioselective synthesis of syn-1,3-diols by the reaction of aldehydes with enol silyl ethers in the presence of a chiral borane complex. Successive asymmetric aldol reaction and asymmetric reduction with one promoter

Yuichi Kaneko, Takao Matsuo, Syun‐ichi Kiyooka

Tetrahedron Letters · 1994 · 40 citations · 11 references

DOI

Concepts

References

11

Nuclear magnetic resonance enantiomer regents. Configurational correlations via nuclear magnetic resonance chemical shifts of diastereomeric mandelate, O-methylmandelate, and .alpha.-methoxy-.alpha.-trifluoromethylphenylacetate (MTPA) esters

James A. Dale, Harry S. Mosher · Journal of the American Chemical Society · 1973 · 2.6K citations

, , +6

Correlation of configuration and fluorine-19 chemical shifts of .alpha.-methoxy-.alpha.-trifluoromethylphenyl acetate derivatives

Glenn R. Sullivan, James A. Dale, Harry S. Mosher · The Journal of Organic Chemistry · 1973 · 504 citations

, , +8

Samarium-catalyzed intramolecular Tishchenko reduction of .beta.-hydroxy ketones. A stereoselective approach to the synthesis of differentiated anti 1,3-diol monoesters

David A. Evans, Amir H. Hoveyda · Journal of the American Chemical Society · 1990 · 411 citations

, , +8

Stereoselective reduction of β hydroxyketones to 1,3-diols highly selective 1,3-asymmetric induction via boron chelates

Koichi Narasaka, Fong-Chang Pai · Tetrahedron · 1984 · 339 citations

, , +7

Enantioselective chiral borane-mediated aldol reactions of silyl ketene acetals with aldehydes. The novel effect of the trialkysilyl group of the silyl ketene acetal on the reaction course

Syun‐ichi Kiyooka, Yuichi Kaneko, Misako Komura et al. · The Journal of Organic Chemistry · 1991 · 197 citations

, , +9